Subject: UV monitors
Yes, there are photo-sensitive papers for UV, although they are not really the best method to use now. During the early days of UV research, they were about the only way of monitoring UV radiation, but now there are many methods that are faster, easier and more precise. Photographic plates may be used, although most are too fast and not UV specific enough for your purposes. A pure silver chloride plate is most specific to UV (although only the near UV), while bromide plates are sensitive in the blue region. Gelatin in unfortunately a good absorber of UV at shorter than 2800 A. Below about 2000 A, gelatin is virtually opaque to UV. Thus the photographic plate or paper is only sensitive up to about 2500 A. It is possible to make salted papers much as they did in the 1840's, but the normal sizing additive to the salting solution is gelatin and another additive would have to be used (another protein or a starch.) In addition, these papers would have to be changed fairly often -- on sunny days, possibly more than once per hour. Also, if your city is quite polluted, they are sensitive to many chemicals in the air, especially sulfur compounds. One approach to extending the UV range of these papers is to add a UV fluorescent chemical such as dihydrocollidine ethyl carboxylate. Another test paper used was made from purified sulfite pulp and dyed with Benzoazurine G. Many of the other chemical detectors require an analytical lab to quantify. Such reactions include the bleaching of a solution of acetone methyelene blue or the decomposition of oxalic acid/uranyl sulfate. In the latter case, a lab is required to quantify the remaining oxalic acid. Other color reactions include (colorless) derivatives of triphenyl-methane dyes, and zinc sulfide in lead acetate (which goes dark.) Most museums use two devices. The first is a lux meter for measuring illuminance. This device is non-specific to UV. The second device is a UV monitor (most commonly, the Crawford UV Monitor), which measures the UV content of light in microwatts per lumen. The lumen (lm) is the SI unit for luminous flux in candela-steradians while the lux (lx) is the SI unit for illuminance in lumens per square meter. (None of this is really important.) Thomson (in The Museum Environment) says that both measures should be considered independently. Sources with a UV content of 75 microwatts per lumen or more should be filtered. Beyond these devices are any number of radiometric devices (including thermopiles, bolometers and radiometers) and photoelectric devices (including phototubes, photovoltaic cells and photoresistance cells). The radiometric devices have no long wave cut-off limit and read right into the IR end. They are also non-spectral sensitive. The photoelectric devices have long wave limits from the UV on into near IR. Photoelectric devices also vary in response depending on wavelength. Because of the long range wavelengths that any of these devices are sensitive to, appropriate filtration, monochromator or diffraction grating should be used (depending on application.) (Monochromators and diffraction gratings allow single or narrow bandwidths to be monitored.) My recommendation is that you follow what other museums do and use a Crawford. However, I have very recently heard that some people who did not like the Crawford although no one was specific about why. -Doug *** Conservation DistList Instance 5:19 Distributed: Sunday, September 8, 1991 Message Id: cdl-5-19-004 ***Received on Sunday, 8 September, 1991