Subject: Common peroxide-forming chemicals
While I was flipping through my newest CRC Handbook of Chemistry and Physics (75th ed) (looking for something else) I came across a good table of solvents with peroxide forming problems. I remember that this came up several months ago due to some surprise chemicals found at HRC (Karen Pavelka.) I noticed at least a few common solvents used in conservation labs (and there are probably more) that I hadn't mentioned when I wrote on this subject before. Since I don't know what people are using in conservation now, I thought that I would quote the whole list. Common Peroxide-Forming Chemicals List A Severe Peroxide Hazard on Storage with Exposure to Air Discard within 3 months Diisopropyl ether (isopropyl ether) Divinylacetylene (DVA) Potassium metal Potassium amide Sodium amide (sodamide) Vinylidene chloride (1,1-dichloroethylene) List B Peroxide Hazard on Concentration; Do Not Distill or Evaporate Without First Testing for the Presence of Peroxides. Discard or test for peroxides after 6 months. Acetaldehyde diethyl acetal (acetal) Cumene (isopropylbenzene) Cyclohexene Cyclopentene Decalin (decahydronaphthalene) Diacetylene Dicyclopentadiene Diethyl ether (ether) Diethylene glycol dimethyl ether (diglyme) Dioxane Ethylene glycol dimethyl ether (glyme) Ethylene glycol ether acetates Ethylene glycol monethers (cellosolves) Furan Methylacetylene Methylcyclopentane Methyl isobutyl ketone Tetrahydrofuran (THF) Tetralin (tetrahydronaphthalene) Vinyl ethers List C Hazard of Rapid Polymerization Initiated by Internally Formed Peroxides a) Normal liquids; Discard or test for peroxides after 6 months Chloroprene (2-chloro-1,3-butadiene_ Styrene Vinyl acetate Vinylpyridine b) Normal Gases; Discard after 12 months Butadiene Tetrafluoroethylene (TFE) Vinylacetylene (MVA) Vinyl chloride -------------------------------- I don't think anyone has anything from list C, but I included it for completeness. MIBK and cellosolves particularly caught my eye in list B. -Doug *** Conservation DistList Instance 5:22 Distributed: Sunday, October 6, 1991 Message Id: cdl-5-22-002 ***Received on Saturday, 5 October, 1991